Term USAFullerene Research
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The Fullerene Group in the Chemistry Department of Moscow State University certifies the fullerenes distributed by Term USA and conducts research on fullerenes and fullerene derivatives.

Contact for Research-Related Questions
Prof. Lev Sidorov
E-mail: sidorov@thermo.chem.msu.ru
Phone: +7(495)9391240, fax +7(495)9391240
Web: http://thermolab.chem.msu.ru
Mailing address:
Thermochemistry Lab
Department of Chemistry
Moscow State University
Leninskie Gory 1-3
119991, Moscow
Russia.

Principal Scientific Interests of the Fullerene Group

  • Preparation and characterization of inorganic fullerene derivatives (S.I. Troyanov, D.Sc.; A.A. Goryunkov, Ph.D.)
  • Ion-Molecular equilibria in the fullerene vapors (A. Y. Borshchevsky, Ph.D.; V.E. ALeshina, Ph.D.)
  • Combustion Calorimetry [formation enthalpy of C60, C70 and fluorofullerenes] (T.S. Papina, Ph.D.)
  • Adiabatic calorimetry (R.M. Varuschenko, D.Sc.) and DSC (N.V. Chelovskaya, Ph.D.)
  • Synthesis of modified phases of fullerite C60 (E.V. Skokan, Ph.D.)
  • Crystal structure of fullerene derivatives (S.I. Troyanov, D.Sc.)
  • HPLC Separation and purification of fullerenes and derivatives (A.A. Goryunkov, Ph.D.; N.B. Tamm, Ph.D.)

Publications 2006-2007

E.I. Dorozhkin, D.V. Ignat`eva, N.B. Tamm, A.A. Goryunkov, P.A. Khavrel, I.N. Ioffe, A.A. Popov, I.V. Kuvychko, A.V. Streletskiy, V.Yu. Markov, J. Spandal, S.H. Strauss, O.V. Boltalina. Synthesis, characterization, and theoretical study of stable isomers of C70(CF3)2,4,6,8,10, Chem. Eur. J., Volume 12, Issue 14, 2006, 3876-3889.

D.V. Ignat`eva, A.A. Goryunkov, N.B. Tamm, I.N. Ioffe, S.M. Avdoshenko, L.N. Sidorov, A. Dimitrov, E. Kemnitz, S.I. Troyanov. Preparation, crystallographic characterization and theoretical study of the two isomers of C70(CF3)12, Chem. Commun., 2006, 1778-1780.

S.I. Troyanov, A. Dimitrov, E. Kemnitz, Selective Synthesis of a Trifluoromethylated Fullerene and the Crystal Structure of C60(CF3)12, Angew. Chem. Int. Ed., 45, 2006, 1971-1974.

A.A. Goryunkov, D.V. Ignat'eva, N.B. Tamm, N.N. Moiseeva, I.N. Ioffe, S.M. Avdoshenko, V.Yu. Markov,L.N. Sidorov, E. Kemnitz, and S.I. Troyanov, Preparation, Crystallographic Characterization, and Theoretical Study of C70(CF3)14, Eur. J. Org. Chem., 2006, 2508-2512.

S.M. Avdoshenko, A.A. Goryunkov, I.N. Ioffe, D.V. Ignat`eva, L.N. Sidorov, P. Pattison, E. Kemnitz, S.I. Troyanov, Preparation, crystallographic characterization and theoretical study of C70(CF3)16 and C70(CF3)18, Chem. Commun., 2006, 2463-2465.

E.I. Dorozhkin, D.V. Ignat`eva, N.B. Tamm, N.V. Vasilyuk, A.A. Goryunkov, S.M. Avdoshenko, I.N. Ioffe, L.N. Sidorov, P. Pattison, E. Kemnitz, S.I. Troyanov, Structure of 1,4,10,19,25,41-C70(CF3)6, isomer with unique arrangement of addends, J. Fluorine Chem., 127, 2006, 1344-1348.

A.V. Kepman, V.F. Sukhoverkhov, A. Tressaud, C. Labrugere, E. Durand, N.S. Chilingarov, L.N. Sidorov, Novel method of synthesis of C60F48 with improved yield and selectivity, J. Fluorine Chem., 127, 2006, 832-836.

A.A. Popov, V.M. Senyavin, S.I. Troyanov, Electronic Structure and Spectroscopic Studies of D3d-C60Cl30, a Chlorofullerene with a [18]Trannulene Ring, and Its Relation to Other [18]Trannulenes, J. Phys. Chem. A, 110, 2006, 7414-7421.

N.B. Shustova, D.Yu. Chernyshev, S.I. Troyanov, Crystal structure of C60Cl6 prepared by a reaction of C60 with POCl3, Mendeleev Commun., 16, 2006, 209-210.

S.I. Troyanov, E. Kemnitz, Singly-Bonded fullerene dimers: neutral (C60Cl5)2 and cationic (C70)22+, Chem. Commun., 2007, p. 2707-2709.

C.B. Hubschle, S. Scheins, M. Weber, P. Luger, A. Wagner, T. Koritsanszky, S.I. Troyanov, O.V. Boltalina, I.V. Goldt, Bond Orders and Atomic Properties of the Highly Deformed Halogenated Fullerenes C60F18 and C60Cl30 Derived from their Charge Densities, Chemistry - A European Journal, 2007, v.13 ,p. 1910-1920.

N.B. Tamm, S.I. Troyanov. Synthesis and molecular structure of seven isomers of C70(C2F5)10. Mendeleev Commun., 2007, p. 172-174.

N.S. Ovchinnikova, D.V. Ignateva, N.B. Tamm, S.M. Avdoshenko, A.A. Goryunkov, I.N. Ioffe, V.Yu. Markov, S.I. Troyanov, L.N. Sidorov, M.A. Yurovskaya, E. Kemnitz. Regioselective synthesis and crystal structure of C70(CF3)10[CO2Et)2], New J. Chem., 2007, p. 121-128.

A.S. Pimenova, A.A. Kozlov, A.A. Goryunkov, V.Yu. Markov, P.A. Khavrel, S.M. Avdoshenko, V.A. Vorobiev, I.N. Ioffe, S.G. Sakharov, S.I. Troyanov, L.N. Sidorov. Preparation and structures of [6,6]—open difluoromethylene[60]fullerenes: C60(CF2) and C60(CF2)2. Dalton Trans., 2007, p. 5322-5328.

A.S. Pimenova, A.A. Kozlov, A.A. Goryunkov, V.Yu. Markov, P.A. Khavrel, S.M. Avdoshenko, V.A. Vorobiev, I.N. Ioffe, S.G. Sakharov, S.I. Troyanov, L.N. Sidorov. Synthesis and characterization of Preparation and structures of difluoromethylene-homo[60]fullerene, C60(CF2). Chem. Commun., 2007, p.374-376.

A.A Goryunkov, I.N. Ioffe, P.A. Khavrel, S.M. Avdoshenko, V.Yu. Markov, Z. Mazej, L.N. Sidorov, S.I. Troyanov. The former "C60F18" is actually a double-caged adduct: (C60F16)(C60), Chem. Commun., 2007, p. 704-706.

E.I. Dorozhkin, A.A. Goryunkov, I.N. Ioffe, S.M. Avdoshenko, V.Yu. Markov, N.B. Tamm, L.N. Sidorov, S.I. Troyanov. Synthesis, structure and theoretical study of lower trifluoromethyl derivatives of [60] fullerene, Eur. J. Org. Chem., 2007, p. 582-594.

A.A. Goryunkov, E.I. Dorozhkin, N.B. Tamm, D.V. Ignat'eva, S.M. Avdoshenko, L.N. Sidorov, S.I. Troyanov. Synthesis and molecular structure of 1,6,11,16,18,24,27,36-C60(CF3)8. Mendeleev Commun., 2007, p. 110-112.

N.A. Omelyanyuk, A.A. Goryunkov, N.B. Tamm, S.M. Avdoshenko, I.N. Ioffe, L.N. Sidorov, E. Kemnitz, S.I. Troyanov. New fluoromethylated derivatives of [60]fullerene, C60(CF3)n with n = 12 and 14. Chem. Commun., 2007, p.4794-4796.

S.I. Troyanov, A.A. Goryunkov, E.I. Dorozhkin, D.V. Ignat'eva, N.B. Tamm, S.M. Avdoshenko, I.N. Ioffe, V.Yu. Markov, L.N. Sidorov, K. Schuerel, E. Kemnitz. Higher fluoromethylated derivatives of C60, C60(CF3)16 and C60(CF3)18. Synthesis, structure and theoretical study. J. Fluorine Chem., 2007, 128, p. 545-551.

Other noteworthy publications

I.S. Neretin, K.A. Lyssenko, M.Yu. Antipin, Yu.L. Slovokhotov, O.V. Boltalina, P.A. Troshin, A.Yu. Lukonin, L.N. Sidorov, R. Taylor. C60F18, a flattened fullerene: alias a hexa-substituted benzene, Angew. Chem., 2001, 112, p. 3411-3414.

O.V. Boltalina, A.Ya. Borschevskiy, L.N. Sidorov, J.M. Street, R. Taylor. Preparation of C60F36 and C70F36/38/40, Chem. Commun., 1996, 529-530.

S.I. Troyanov, P.A. Troshin, O.V. Boltalina, I.N. Ioffe, L.N. Sidorov, E. Kemnitz. Two isomers of C60F48: an indented fullerene, Angew. Chem. Int. Ed., 2001, 40, 2285-2287.

O.V. Boltalina, V.Yu. Markov, P.A. Troshin, A.D. Darwish, J.M. Street, R. Taylor. C60F20: "Saturnen", an Extraordinary Squashed Fullerene, Angew. Chem., 2001, 113, 809-811.

P.A. Troshin, R.N. Lyubovskaya, I.N. Ioffe, N.B. Shustova, E. Kemnitz, S.I. Troyanov. Synthesis and Structure of the Highly Chlorinated [60]Fullerene C60Cl30 with Drum-Shaped Carbon Cage, Angew. Chem. Int. Ed., 44, 2005, 234-237.

A. Ya. Borschevskii, L.N. Sidorov, N.S. Chilingarov, and V.E. Aleshina. Topochemical solid-state reactions and problems of selective synthesis of fullerene derivatives, Russian Chemical Bulletin, Int. Ed., Vol. 54, No. 1, 31-50.

L.N. Sidorov, O.V. Boltalina. Endohedral metal derivatives and exohedral fluorine derivatives of fullerenes, Rus. Chem. Rev., 71, 2002, 611-640.


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